Lecture 25. Optimizing H2+ Molecular Orbital, H2, and Configuration Interaction

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Identifiers

10.5446/18904 (DOI)

Publisher

University of California Irvine (UCI)

Release Date

2014

Language

English

Content Metadata

Subject Area

Chemistry

Genre

Lecture

Abstract

UCI Chem 131A Quantum Principles (Winter 2014) Instructor: A.J. Shaka, Ph.D Description: This course provides an introduction to quantum mechanics and principles of quantum chemistry with applications to nuclear motions and the electronic structure of the hydrogen atom. It also examines the Schrödinger equation and study how it describes the behavior of very light particles, the quantum description of rotating and vibrating molecules is compared to the classical description, and the quantum description of the electronic structure of atoms is studied. Index of Topics: 0:03:28 Polarization 0:12:33 H2 0:15:50 Molecular Orbitals for H2 0:18:24 The Potential Energy Curve 0:20:19 The LCAO-MO Problem 0:31:50 The Valence Bond Approach 0:40:28 Wrapping up H2 0:45:53 Bond Order 0:47:28 Comparing H2+ Through He2