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48:53 University of California Irvine (UCI) English 2013

Lecture 01. Chemical Equilibrium Pt. 1.

UCI Chem 1C General Chemistry (Spring 2013) Lec 01. General Chemistry -- Chemical Equilibrium -- Part 1 Instructor: Ramesh D. Arasasingham, Ph.D. UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:12:18 Calculate Species at Equilibrium 0:25:24 Writing Law of Mass Action (Kc) 0:37:17 Steps for Writing Law of Mass Action
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
29:06 University of California Irvine (UCI) English 2013

Lecture 26. Chemical Kinetics Pt. 5.

UCI Chem 1C General Chemistry (Spring 2013) Lec 26. General Chemistry -- Chemical Kinetics -- Part 5 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Experimentally Measured Rate Law Review 0:03:02 Factors that Affect a Rate 0:09:43 Reaction Profile 0:14:13 More on Collision Theory 0:21:12 Arrhenius Equation
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:53 University of California Irvine (UCI) English 2013

Lecture 25. Chemical Kinetics Pt. 4.

UCI Chem 1C General Chemistry (Spring 2013) Lec 25. General Chemistry -- Chemical Kinetics -- Part 4 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Brief Review of Rate Law 0:03:07 Reaction Mechanism 0:10:00 Molecularity 0:15:39 Intermediates 0:18:21 Speed of reaction 0:21:59 Overall Reaction Example 0:32:00 Kinetics and Chemical Equilibrium 0:36:54 Experimentally Measured Rate Law 0:44:26 Rate Law Example Given Experiment Concentrations
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:32 University of California Irvine (UCI) English 2013

Lecture 13. Aqueous Equilibria Pt. 2.

UCI Chem 1C General Chemistry (Spring 2013) Lec 13. General Chemistry -- Aqueous Equilibria -- Part 2 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:03:25 Weak Base vs. Strong Acid Example 0:07:04 pH Titration Curve Picture 0:12:10 Understanding Strong Acid Neutralizing Weak Base 0:14:33 Solubility Product 0:22:24 "Insoluble" Salts 0:26:26 Introducing Ksp 0:35:50 Rules ofr Solubility in Water 0:41:14 Solubility and Ksp
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:45 University of California Irvine (UCI) English 2013

Lecture 21. Electrochemistry Pt. 6.

Ramesh D. Arasasingham, Ph.D.UCI Chem 1C General Chemistry (Spring 2013) Lec 21. General Chemistry -- Electrochemistry -- Part 6 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:50 Ecell and K 0:04:25 Calculate K for the Equilibrium... 0:12:40 Nerst Equation 0:17:47 Calculate Potential of Daniell Cell 0:23:01 Galvanic Cell Review 0:29:52 Electrolysis (Electrolytic Cell) 0:42:52 Amounts of Products of Electrolysis
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
52:04 University of California Irvine (UCI) English 2013

Lecture 23. Chemical Kinetics Pt. 2.

UCI Chem 1C General Chemistry (Spring 2013) Lec 23. General Chemistry -- Chemical Kinetics -- Part 2 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Review on Rates 0:04:02 Kinetic Rate Laws 0:08:57 Example Using N2O5 0:15:53 Determining Rate Law and Order for Reaction 0:28:16 Determing Rate Expression and Value of the Constant 0:42:56 Measuring Rate of Chemical Reaction with Graphs
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
53:18 University of California Irvine (UCI) English 2013

Lecture 24. Chemical Kinetics Pt. 3.

UCI Chem 1C General Chemistry (Spring 2013) Lec 24. General Chemistry -- Chemical Kinetics -- Part 3 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Integrated Rate Law Intro 0:02:48 First order Reaction for Integrated Rate Law 0:04:58 Half Life 0:10:22 Finding Rate Constant for First Order Reaction 0:18:05 Second Order Reaction 0:25:19 Finding Concentration if Given Initial Concentrations 0:31:06 Zero Order Reaction 0:40:47 Summary of Kinetic Reactions 0:43:49 Integrated Rate Laws for Reactions with More than One Reactant
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:59 University of California Irvine (UCI) English 2013

Lecture 06. Acids and Bases. Pt. 3.

UCI Chem 1C General Chemistry (Spring 2013) Lec 06. General Chemistry -- Acids and Bases -- Part 3 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:01:36 Summary of Bases 0:04:51 Review of Equilibria 0:13:03 Calculating pH of Solution 0:19:45 Polyprotic Acids 0:20:40 Monoprotic Acids 0:23:59 H2SO4 Example 0:33:21 h2CO3 Example 0:41:14 Finding Concentration of Polyprotic Acids
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:23 University of California Irvine (UCI) English 2013

Lecture 07. Acids and Bases. Pt. 4.

UCI Chem 1C General Chemistry (Spring 2013) Lec 07. General Chemistry -- Acids and Bases -- Part 4 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Review of Carbonic Acid Example 0:15:43 Hydrolysis 0:18:10 Acid Base Properties of Salt 0:39:00 Calculating pH of Salt 0:47:09 Arranging Compounds from Most Acidic to Most Basic
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
48:54 University of California Irvine (UCI) English 2013

Lecture 02. Chemical Equilibrium Pt. 2.

UCI Chem 1C General Chemistry (Spring 2013) Lec 02. General Chemistry -- Chemical Equilibrium -- Part 2 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:01:58 Using Reverse Reactions and Limiting Reagents 0:05:17 Percent Decomposition 0:07:41 Acid Base Equilibria 0:10:14 Examples of Acids 0:16:58 Bronsted Lowry Definition 0:18:14 Example Using Water 0:26:33 Defining "Conjugate Acid" 0:30:26 Conjugate Acid Examples 0:32:59 Introducing Acid Dissociation 0:37:27 HCl and Water Example 0:41:24 NH2- in Water Example
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:14 University of California Irvine (UCI) English 2013

Lecture 11. Buffered Solutions (Buffers) Pt. 2.

UCI Chem 1C General Chemistry (Spring 2013) Lec 11. General Chemistry -- Buffered Solutions -- Part 2 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Titrations Review 0:10:14 Types of Titration 0:11:47 Strong Acid added to Strong Base Titration 0:32:35 Strong Base added to Strong Acid Titration 0:46:21 Finding Volume of Excess OH-
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:13 University of California Irvine (UCI) English 2013

Lecture 05. Acids and Bases. Pt. 2.

UCI Chem 1C General Chemistry (Spring 2013) Lec 05. General Chemistry -- Acids and Bases -- Part 2 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:01:27 Weak Acids Dissociate Partially 0:06:18 Summary of Ka and Strength of Acid 0:12:00 Bases Overview 0:14:20 NH2- and Strong Base Example 0:20:23 Weak Base NH3 Example 0:37:55 Rankning COmpounds Based on Base Strength 0:47:46 Weak Acid/Base Equilibria
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:08 University of California Irvine (UCI) English 2013

Lecture 04. Acids and Bases. Pt. 1.

UCI Chem 1C General Chemistry (Spring 2013) Lec 04. General Chemistry -- Acids and Bases -- Part 1 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:01:31 pH Review 0:05:10 Determining if Solution is Acidic 0:06:52 Strong Acid Characteristics 0:08:22 Showing HCl as a Strong Acid 0:15:00 Percent Undissociated 0:18:51 Finding pOH 0:25:25 Weak Acids 0:27:22 CH5CO2H Example 0:38:24 Ka/pKa Table 0:47:25 Determine if Solution is Basic 0:48:49 Strong Bases
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:34 University of California Irvine (UCI) English 2013

Lecture 14. Aqueous Equilibria Pt. 3.

UCI Chem 1C General Chemistry (Spring 2013) Lec 14. General Chemistry -- Aqueous Equilibria -- Part 3 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Equilibria Review 0:03:44 Calculating Ksp 0:10:40 Precipitation of Solubility Product 0:14:35 Complete Ion Equation 0:26:40 Precipitation Reaction 0:38:29 Calculating Concentration at Equilibrium 0:46:47 Common Ion Effect
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:55 University of California Irvine (UCI) English 2013

Lecture 09. Acids and Bases. Pt. 6.

UCI Chem 1C General Chemistry (Spring 2013) Lec 09. General Chemistry -- Acids and Base -- Part 6 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Common Ion Effect Review 0:03:35 Buffered Solutions 0:09:20 Examples of Buffers 0:15:07 How Does a Buffer Work? 0:32:24 Calculating the pH of the Buffer
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:13 University of California Irvine (UCI) English 2013

Lecture 10. Buffered Solutions (Buffers) Pt. 1.

UCI Chem 1C General Chemistry (Spring 2013) Lec 10. General Chemistry -- Buffered Solutions (Buffers) -- Part 1 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:05:18 Identifying Buffers 0:11:20 Weak Acid and Salt Example 0:17:23 What Makes this a Buffer? 0:22:23 Calculating the pH of a Buffered Solution 0:27:22 Designing Buffers at Specific pH Values 0:44:34 Acid Base Titration Curves
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
48:22 University of California Irvine (UCI) English 2013

Lecture 08. Acids and Bases. Pt. 5.

UCI Chem 1C General Chemistry (Spring 2013) Lec 08. General Chemistry -- Acids and Bases -- Part 5 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Putting Salt in Water Review 0:05:50 NaCl Example 0:09:41 Anion Possibilities 0:11:48 Calculating pH of NH4Cl 0:21:10 Acid in Water 0:27:06 Common Ion Effect 0:37:06 Calculating % Dissociation Common Ion Effect
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:02 University of California Irvine (UCI) English 2013

Lecture 12. Aqueous Equilibria Pt. 1.

UCI Chem 1C General Chemistry (Spring 2013) Lec 12. General Chemistry -- Aqueous Equilibria -- Part 1 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Review on Strong Acid/Strong Base Titration 0:05:14 Weak Acid and Strong Base Titration 0:10:10 General Reaction 0:13:45 Titration Curves 0:19:04 Calculating pH before any Base is Added 0:31:29 pH at Equivalence Point 0:38:46 pH of a Weak Base 0:44:55 Titration Curve Concept
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
53:23 University of California Irvine (UCI) English 2013

Lecture 17. Electrochemistry Pt. 2.

UCI Chem 1C General Chemistry (Spring 2013) Lec 17. General Chemistry -- Electrochemistry -- Part 2 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Balancing Redox Reaction Review 0:14:46 Balancing Redox Reaction in Acidic or Basic Solution 0:19:07 Balancing Redox in Acidic Aqueous Solution 0:23:46 Rules for Balancing in Acidic/Basic Aqueous Solution 0:34:18 Example in Basic Aqueous Solution 0:47:56 Example in Acidic Solution
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:07 University of California Irvine (UCI) English 2013

Lecture 16. Electrochemistry Pt. 1.

UCI Chem 1C General Chemistry (Spring 2013) Lec 16. General Chemistry -- Electrochemistry -- Part 1 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Oxidation Reduction Reaction Review 0:02:55 Oxidation Numbers 0:04:50 Rules for Assigning Oxidation Numbers 0:10:13 Calculating Oxidation Number Example 0:16:26 Redox Reactions 0:17:10 Half Reactions 0:23:09 Example of Redox Reactions 0:37:58 Balancing Oxidation-Reduction Reactions 0:47:04 Challenging Redox Question
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:32 University of California Irvine (UCI) English 2013

Lecture 18. Electrochemistry Pt. 3.

UCI Chem 1C General Chemistry (Spring 2013) Lec 18. General Chemistry -- Electrochemistry -- Part 3 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Review of Acidic/Basic Solutions 0:01:58 Spontaneous Electrochemistry Reactions 0:09:15 Galvanic (Voltaic) Cell 0:14:43 Example Using Batteries 0:21:53 Daniell Cell and Intro to Anode/Cathode 0:36:11 Electrodes 0:43:28 Shorthand notation for Cells
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:30 University of California Irvine (UCI) English 2013

Lecture 15. Aqueous Equilibria Pt. 4.

UCI Chem 1C General Chemistry (Spring 2013) Lec 14. General Chemistry -- Aqueous Equilibria -- Part 4 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Common Ion Effect Review 0:01:45 Finding Solubility of Compound Given Ksp 0:09:05 Effect of pH on Solubility 0:16:52 Solubility of Metal Salts of the Conjugate Bases of Weak Acids 0:20:05 Solubility of Metal Salts of the Conjugate Bases of Strong Acids 0:23:32 Finding Solubility of Compound in Buffered Solution 0:38:15 Electrochemistry 0:42:52 Oxidation Reduction Reactions
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:10 University of California Irvine (UCI) English 2013

Lecture 19. Electrochemistry Pt. 4.

UCI Chem 1C General Chemistry (Spring 2013) Lec 19. General Chemistry -- Electrochemistry -- Part 1 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00: Galvanic Cells/Daniel Cell Review 0:04:54 Hydrogen Electrode 0:07:54 Cell Notation Example 0:19:40 Cell Potential, Voltage, Electromotive Force 0:25:34 Cell Potential and Free Energy 0:33:48 Reaction of N2 and H2 0:38:45 If Reaction is under Standard Conditions 0:48:10 Standard Reduction Potentials
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:15 University of California Irvine (UCI) English 2013

Lecture 03. Chemical Equilibrium Pt. 3.

UCI Chem 1C General Chemistry (Spring 2013) Lec 03. General Chemistry -- Chemical Equilibrium -- Part 3 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:02:02 Aqueous Acids/Bases 0:04:42 Determining which is Acid/Base/Ca/Cb 0:07:04 Autoionization of Water 0:21:06 Introducing "pH" 0:27:09 Finding COncentration from pH 0:30:59 pH and Concentration Relationship 0:42:32 Acid Equilibrium
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:34 University of California Irvine (UCI) English 2013

Lecture 20. Electrochemistry Pt. 5.

UCI Chem 1C General Chemistry (Spring 2013) Lec 20. General Chemistry Electrochemistry, Part 5 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:03:29 Review of Cell Potential 0:06:06 Standard Reduction Potential of Standard Electrode 0:13:15 Finding Cell Potential Example 0:26:13 Significance of Standard Reduction Potentials 0:38:02 Can Aqueous KMnO4 Oxidize Iron? 0:44:49 Standard Potentials and Equilibrium Constants
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:41 University of California Irvine (UCI) English 2013

Lecture 22. Chemical Kinetics Pt. 1.

UCI Chem 1C General Chemistry (Spring 2013) Lec 22. General Chemistry -- Chemical Kinetics -- Part 1 Instructor: Ramesh D. Arasasingham, Ph.D. Description: UCI Chem 1C is the third and final quarter of General Chemistry series and covers the following topics: equilibria, aqueous acid-base equilibria, solubility equilibria, oxidation reduction reactions, electrochemistry; kinetics; special topics. Index of Topics: 0:00:00 Change in Free Energy Review 0:01:40 Intro to Chemical Kinetics 0:06:43 Defining Chemical Kinetics 0:09:57 Reaction Rate 0:15:02 Example of Reaction Rate 0:24:41 Average Rate of Concentration vs Time 0:34:13 Example of NO Gas Reaction Rate 0:40:08 Relationship Between Reaction Rates 0:47:57 Forward/Reverse Reactions
  • Published: 2013
  • Publisher: University of California Irvine (UCI)
  • Language: English
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