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A GCS NO2 Camera image series of the emissions of the Großkraftwerk Mannheim (coloured)

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A GCS NO2 Camera image series of the emissions of the Großkraftwerk Mannheim (coloured)
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CC Attribution 3.0 Germany:
You are free to use, adapt and copy, distribute and transmit the work or content in adapted or unchanged form for any legal purpose as long as the work is attributed to the author in the manner specified by the author or licensor.
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Production Year2021
Production PlaceHeidelberg, Germany

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Abstract
Spectroscopic methods have proven to be reliable and of high selectivity by utilizing the characteristic spectral absorption signature of trace gases such as NO₂. However, they typically lack the spatio-temporal resolution required for real-time imaging measurements of NO₂ emissions. We propose imaging measurements of NO₂ in the visible spectral range using a novel instrument, an NO₂ camera based on the principle of Gas Correlation Spectroscopy (GCS). For this purpose two gas cells (cuvettes) are placed in front of two camera modules. One gas cell is empty, while the other is filled with a high concentration of the target gas. The filled gas cell operates as a non-dispersive spectral filter to the incoming light, maintaining the two-dimensional imaging capability of the sensor arrays. NO₂ images are generated on the basis of the signal ratio between the two images in the spectral window between 430 and 445 nm, where the NO₂ absorption cross section is strongly structured. The capabilities and limits of the instrument are investigated in a numerical forward model. The predictions of this model are verified in a proof-of-concept measurement, in which the column densities in specially prepared reference cells were measured with the NO₂ camera and a conventional DOAS instrument. Finally, results from measurements at a large power plant, the Großkraftwerk Mannheim (GKM), are presented. NO₂ column densities of the plume emitted from a GKM chimney are quantified at a spatio-temporal resolution of 1/12 frames per second (FPS) and 0.9 m × 0.9 m. A detection limit of 2·10¹⁶ molec cm⁻² was reached. An NO₂ mass flux of Fₘ = (7.4 ± 4.2) kg h⁻¹ was estimated on the basis of wind speeds obtained from consecutive images. The instrument prototype is highly portable for building costs of below 2,000 Euro.
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