One pot synthesis of a cyclodextrin polyrotaxane and formation of a slide-ring gel

Video thumbnail (Frame 0) Video thumbnail (Frame 609) Video thumbnail (Frame 1096) Video thumbnail (Frame 1385) Video thumbnail (Frame 1612) Video thumbnail (Frame 1944) Video thumbnail (Frame 2365) Video thumbnail (Frame 2631) Video thumbnail (Frame 2935) Video thumbnail (Frame 3145) Video thumbnail (Frame 3332) Video thumbnail (Frame 3513) Video thumbnail (Frame 4008) Video thumbnail (Frame 4222) Video thumbnail (Frame 4545) Video thumbnail (Frame 4758) Video thumbnail (Frame 5073) Video thumbnail (Frame 5299) Video thumbnail (Frame 5555) Video thumbnail (Frame 5762) Video thumbnail (Frame 5974) Video thumbnail (Frame 6349) Video thumbnail (Frame 6576) Video thumbnail (Frame 6796) Video thumbnail (Frame 7038) Video thumbnail (Frame 7313) Video thumbnail (Frame 7585) Video thumbnail (Frame 8027) Video thumbnail (Frame 8337) Video thumbnail (Frame 8522) Video thumbnail (Frame 8782) Video thumbnail (Frame 9173) Video thumbnail (Frame 9361) Video thumbnail (Frame 9585) Video thumbnail (Frame 9772) Video thumbnail (Frame 10208) Video thumbnail (Frame 10608) Video thumbnail (Frame 10841) Video thumbnail (Frame 11211) Video thumbnail (Frame 11549) Video thumbnail (Frame 11755) Video thumbnail (Frame 11966) Video thumbnail (Frame 12168) Video thumbnail (Frame 12359) Video thumbnail (Frame 12539) Video thumbnail (Frame 13679)
Video in TIB AV-Portal: One pot synthesis of a cyclodextrin polyrotaxane and formation of a slide-ring gel

Formal Metadata

One pot synthesis of a cyclodextrin polyrotaxane and formation of a slide-ring gel
CC Attribution - NoDerivatives 4.0 International:
You are free to use, copy, distribute and transmit the work or content in unchanged form for any legal purpose as long as the work is attributed to the author in the manner specified by the author or licensor.
Release Date

Content Metadata

Subject Area
Polyrotaxanes are molecular entities in which many rings are threaded onto a polymer chain with attached stopper groups hindering the rings from dissociation. Polyrotaxanes were synthesized from isoprene, styrene and cyclodextrins through a one pot reaction in water similar to an emulsion polymerization. The product can be isolated simply by heat filtration. Slide-ring gels are obtained by cross-linking of the threaded cyclodextrins using diisocyanates.
Keywords reactions cyclodextrins
Waterfall Island Germanic peoples Biosynthesis Erdrutsch Chemistry Hope, Arkansas
Stop codon Impfung <Chemie> Taxane Electrical mobility Chemical experiment Chemical property
Glucose Molecule Water Starch Polymer Zunderbeständigkeit Wasserbeständigkeit Multiprotein complex Solubility
Systemic therapy Kohlenhydratchemie Chain (unit) Elektrolytische Dissoziation Azo coupling Chemical experiment Multiprotein complex
Water Metal Initiation (chemistry) Radical (chemistry) Chemical experiment Solution Multiprotein complex Wine tasting descriptors
Chemical experiment
Kalisalze Stickstoffatom Chemical experiment Chemical compound Cobaltoxide Multiprotein complex
Chemical experiment
Volumetric flow rate Systemic therapy Stickstoffatom Anaerobic digestion Chemical experiment Cobaltoxide Multiprotein complex Solution
Survival skills Curing (food preservation) Chemical experiment Suspension (chemistry) Chemical reaction Solution Spawn (biology) Pressure Fuel oil
Chemical experiment
Systemic therapy Natural rubber Chemical experiment Filtration
Chemical experiment Chemical reaction
Chemical experiment
Stop codon Optische Aktivität Sense District Sample (material) Combine harvester Agriculture Match Misoprostol Taxane Colourant Medical history
Chemical experiment
Optische Aktivität Sample (material) Functional group Concentrate Chemical experiment
Sense District Dyeing Sample (material) Impfung <Chemie>
Sense District Sample (material) Concentrate Chemical experiment
Chemical experiment
Sample (material) Chain (unit) Materials science Chemical experiment Plant breeding
Chain (unit) Functional group Octane rating Chemical experiment Chemical reaction Chemistry
Flüchtigkeit Intergranular corrosion Chloroform Chemical experiment Wursthülle Chemistry
Impfung <Chemie> Chemical experiment Mixture Solution
Chemical experiment
Chemical experiment Thermoforming
Chemical experiment Chemical reaction Extract
Chemical experiment
Biosynthesis Agriculture Selenite Radical (chemistry) Materials science Chemical experiment ISO-Komplex-Heilweise
i didn't buy. the hope is a guy. week michael manipulate chemistry he its island cuny was the key insight putting germany we found in you want pots indices fall point it would take saints.
put your texts aims are more likely to end the tees in which many is things as rated on a pony michie in and said name comes from the ability of submarines to rotate and on supporting me and x's so remains can also move.
along it but say i he net from sliding off by paepke stop posts shown in through here. because of says restricted mobility bollywood taxanes show very interesting material properties despite polio vaccines are norm for more than twenty years at the k. shuns asked to rate their because soon this is his.
very tedious and expensive but the far and much more simple message to send a size polio taxanes starting from commodity chemicals like eyes so premium stier remain and psycho to extremes cycle.
but extremes are cyclical eco mayors of glucose which approach used by and cinematic take with asian of starch in industrial scale cycle of extremes i able to complex hydrophobic guest molecules in border we have chosen and made too late.
it's i could extreme derivative called our map because it's much better soluble in water send native psychotic stream of our map allows to soluble lies eyes open remain in water and to perform radical polymer is asians leading.
directly to polly road accidents. hello i'm going to carry and here in this lab we are working with cyclists in baseball or of excellence in our system the second extreme complex as a brain couple human eyes the villa very small amount of staring common among which is large enough to prevent this association of the second sugar and the polyamory chain.
we're using metal a to b. to settle their three unjustly improve the water celebrity of the resulting complex this sort of six grams of meditated be the secularists in tandem elite of water and get clear solution the the soviet zero forty four tamar radical initiator in this echoes sadly that's when solution.
and then add the standing woman staring designed for the compound so we have been that these saw them border but second taxing complexes and so belies stammering then i bubble true nitrogen for twenty to thirty minutes in order to remove the oxygen is particularly important sea.
and oxygen in the beats freely couple imitation i can ads as a print only after d.'s there's oxygenation because nitrogen flow can remove the work that as a brain from the system than we have to wait several minutes to get clear solution that means that although as a praying complex and so.
mobilized in this cycle solution than the custody reaction just put it into a pressure heated oil gas and certifies as agree and finally after two days we have the product to survive fish market suspension this is very stable suspension since most of the mentation of cures after even weeks or mounds.
is just like nature rubber latics the work up is also very simple is just the heat filtration so it means i heat up the system to eighty says his degree and them feel better of after this work a procedure we got around the bank gram of product that's ninety five person.
year based on as a pain free and that's you can see here the can ask your the reaction to get even dances grams of failure of taxing.
hello my name is jessica hedge fund and i will tell us something about analytics of this new products aimed which isn't very important part of our research and mark is the first evidence that we have pointed out taxanes because beside the rom of signals as you can see here we also have the poor as a korean signal here we use and.
in our to calculate the thriving year to follow up or he wrote back saying they'll fall we need and to cut off all rahm of signal here.
and all the party as a prim units here with these two in to cross we calculate just reading view of our exact match that to determine the fretting you'd have all put your taxanes we use a combination of parliament three and from a sense measurements so let's stop with the plot and the tree.
with color imagery we get the total amount else i could extend and our sample cytotec students have a specific optical activity and this is not changing of the side of history must read it or not it's a very simple and foster to take a method which is to solve our sample of a global farm and then.
we measured the optical rotation value was described it with the calibration cars off the around them where you can see the rotation anger as a full function of concentration they can calculate the total amount of psychics in our sample very easy now that we have all our total amount also acted like soon we need to figure out how much.
recycle vaccine we have left in our sample therefore all the e.u. is through a sense measurement with c.n.n.'s ten s. and hydrophobic die which generates of through a sense that now why forming a hospice called reckless be just like that experience to as itself shows almost no through a sense taken as you can see here as our reference.
like with poetry we measure collaboration calls with no in concentrations of sex objects tunes and at to s. are some who sells almost no for a sense because the general we have only three to five percent cited this thing left in our sample from those to analyze as so from poetry and from the through a sense.
measurement they can calculate this wedding you'd have our sample which coalesce well with our animal results. hello i'm has been to induce experiment i will demonstrate how to cross linked to pull the rug seems to have team so-called sloping do this do some of the materials to grow slings are not connected to the parliament chain but to threats like to the extremes therefore the crossings are not fixed and freely mover.
longer palmer chain what gives us an extremely soft and very flexible material from across linking reaction the main focus on your with in chemistry with chance to say needs those can react with the remaining free had received groups of the threaded around meant to connect to put the rate of scenes first to put the rhetoric say.
in his deserved an unknown are simply pull our preferred the price of and like missile in clear eyed of chloroform because of the what the sensitivity of the euro think chemistry in this case we're using chloroform because of volatiles.
it can be removed easily to get a pure mixture of to to react and it's the polio vaccine has to be completely sunday been in the children servant to obtain a highly concentrated solution to cross linking agent take some isn't in that as a sane eight is added to the solution mixed a bit and cost to the.
clothes and heated up to eighty degrees celsius for three days after the reaction the son of a part of the jail is removed by a two day extraction in missing link the right the resulting jail.
his various of and flexible. let's conclude the show it you'll earn your way to synthesize pod eurotech saints by radical polyamory sation of style green eyes so preen and make the late it cyclo to extremes season you'll probably wouldn't say nz can be costly.
st to farm innovative rubbery materials in future we want to develop smart coatings based on these hollywood dec saints for new products showing self healing properties are.