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Nanocar Race 2017: 4. Driving the Nanocar – Manipulation of single molecules

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Nanocar Race 2017: 4. Driving the Nanocar – Manipulation of single molecules
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4
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163
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CC Attribution - NoDerivatives 4.0 International:
You are free to use, copy, distribute and transmit the work or content in unchanged form for any legal purpose as long as the work is attributed to the author in the manner specified by the author or licensor.
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How can you move a single molecule? We could use our tip like a finger and push the nanocar. Actually this would also be possible at the nanoscale! In this case the tip needs to touch the molecule. But pushing the nanocar in this way is forbidden at the Nanocar Race. Only electric power is allowed! As we have shown before there is a tunneling current between tip and sample. We can use this current to inject electric power into the nanocar. The molecule has different energy levels. Without any influence the molecule is in the ground state. If you change the voltage between the tip and the molecule, you can inject electrons in the excited state of the molecule. So it has a higher energy. By filling more and more electrons in the molecule which is done by ramping the bias voltage we also excite states where the molecule does vibrations or rotations. And then it moves. We can control the direction of the movement by the position where we place the tip. The molecule always follows our tip when we inject electrons. So we know exactly where the molecule goes. But then we have to scan again to see the molecule. Because we know where the molecule went after excitation, we can choose a small scan range around this area to get a quick image. The time for a scan is quite long in comparison to the electron injection. By choosing a small scan range at the right position we reduce the time we need to finish the race track at the Nanocar Race.
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