Natural icicles often exhibit ripples about their circumference which are due to a morphological instability. We present an experimental study that explores the origin of the instability, using laboratory-grown icicles. Contrary to theoretical expectations, icicles grown from pure water do not exhibit growing ripples. The addition of a non-ionic surfactant, which reduces the surface tension, does not produce ripples. Instead, ripples emerge on icicles grown from water with dissolved ionic impurities. We find that even very small levels of impurity are sufficient to trigger ripples, and that the growth speed of the ripples increases very weakly with ionic concentration.