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Electron transfer reactions and redox potentials in GALVANIc cells - what happens to the ions at the phase boundary (NERNST, FARADAY)

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this gentleman who would like to welcome you to our cause physical chemistry 101 my name is Dr. Nobel and our topic today is electrochemistry thought to have occasionally edit the and and tension that place to add it
moves into possibly oblige a lot of research and manager but power the current frame is caused by the migration of iron which can be quantified by the ionic mobilities and ionic conductivity however what happens to the eye and at the end of the in the cell secured atoms to false all voluntarily from left to right
on the left hand side of of the plot and chance-most flow from the lecture I in the matter if the genetics is called and hang out on the right hand side through Edmund flow out of the metal in the this is a new is called the cat attend those is characterized in that atoms move from the electron conduct of the ion and I know characterize it plans move from another Yonli that into Linotronic
note capital cannot be generally described as positive or negative the polarity depends on the and low passes freely they go back says that there and always falls in integrated set the change of product on and anecdote is expressed by the so-called and on transfer reaction at the Capitol enough that our species takes a long problematic and that turned into a reducing species at the end of the reverse from interviews species it is therefore on the metal and becoming offered us and it can fill is always covered with an oxidation is the loss of on catalytic current is almost covered with reductions in usually graph reaction written with the electrons on the left in letter words of Cocke I
chlorine is produced the at the positive tone so the following oxidation reaction takes place and then come back real the the negative terminal dissolved in this oxidation reaction those processes take place at the end in activities that you have positive tunnel in this case
oxidation is involved for the that cell the NLU the negative tone oxidation proceeds Laurent Allen in the roses of copper chloride copper G at the new time the following reduction process takes place in the back led to read the reduction of that fall that to celebrate explained at the polluted terms individual is that it
actually isn't fall a couple of negative with the last cell reduction runs 1 carries a cash is wasn't in this thing call battery the negative terminal is the in that result in the
negative tone of in the past as for
any other reactions but also image really hold but it on in particular we need just fundamental not let you will all time news that even and don't have a shot of news at the time as being a part of a constant correspondingly the ratio of current flowing I atrocities and you fill each time and is the amount of substance and which is deposited on the electrodes or sorts this is Faraday's law which applies to both ecology and events the very constant corresponds to the charge on 1 mole of not 6 thousand 400 and 85 criminals per mole if you allow for example a current of 1 cf. Freudenthal 1 day the corresponds to 0 comma decimal 8 9 5 moles of we have 2 modes electron to deposit 1 mole copy we want to hold on to this or that 1 1 observer and remove over time but it was at 1 mole of that so what to various long term when a grand couple 96 strands of silver and 8 grams of would considered to merit couple
and the I answer feel more common convertability couple or with can be expressed by the chemical potential
if you put the 2 methods and contact and I will move from the left Nobel fingers the more noble Cocke but but the cost will their negative charge in respect it would appear that jumping electric potential at based on
similarly we obtain a potential job if you're a combination of the joint under that and ionic conductor John and the if in the cover sheet into a
couple arrived in motion to processes occur cover and
deposit is common to both producing that from low in the direction of the electron come after the fall of the Iron what it was real into the mad because copper is known battle that have car and green arrow initially out way you know the Congress charged positively wanted in life there is a need to but the current will slow down the axon thinking in Italy current will be accelerated eventually in equilibrium disillusioned they and their position they are equal but will result in of tangent
jump and the model of right so
initially the move was polarized have but couple current then the I thought minded as greater than another current density by itself it and agree with and all that kind of current density is equal magnitudes and corresponds to the so-called change current density I not next to it is best
characterized by the so called electrochemical dowdily similar structure to the capacity we move a positive test charge from the electoral line into the matter and record of energy we potential diagram the attainable attention John news electrochemical the the difference in potential between the metal and the electron is referred to as and you put a tension that top 5 in the current list the really state that if I ask all of the rhetoric potential he said wreck every place of think blatantly involve a solution and other can't
should all we can the solution where a lot of repetition rate and the matter charges up negative
again it will be on the end of it and have a current density would the the red
potential all men to panel a reagent that ball and for the copper is
more noble and think that's has more quality their action furthermore all ready potentially does depend on the concentration all all reagents involved in the transfer
come to the 1 loaded right at the rest potential of the points we fall the but topic of his field 1 1 mode of the UK and the US attention of you look point the 1 of the radiation at handling
potential is described by the Nance equation what are the most important the equations in electrochemistry and they're not equation really already is used in advance the reaction can be found this
document number of electrons from you that we have to be included in the 9th spectra what she always knew and the item and other relevant the concentrations of all oxidizing species can be found in the numerator and the concentrations of the reduced species in the denominator the standard potential you
not of the original this
heavily in the characters the chemical potential in general the matter of the tendency of of the species to quite a job and that I would use the but highly erratic problems out
the a gradient is an act on Tolo so permanent
in this paper the the most positive punch the largest and John Paul in a population this imagined it at the bottom of this and that has the largest and push what it on pressure automatically each rejection is entitled wonderful and how if you go online to read a couple the top half reaction with a more positive potential proceeds from there 2 right and the reduction and the bottom half reaction with a negative potential from right to left as an oxidation Hi altered got low or high snatches news editor depending on the what kind generally oxidized and reduced species we distinguish between several types of operations melody roads reference electrodes non-metal edit rules and red and you here
those oxidized and use phone call the reader's couple on its own in the also needed in a
funny conducted to measure their outcome push or pull 11 the eye to and from
the attitudes and examples of reaching the the formulated as potential all the electoral using known degrees at a chemical theory that is bad potential of Europe wall the
fact that music is 1 marked in blue we got a commendation of times the last time in the numerator and this is the oxidized form and the concentration of and 2
goes on in the denominator reduce because I had to go and find me because I saw species we have use modularity was a concentration most of the year the concentrations of iron 2 plus and on the at equal we measure the standard potential E not of new ones and more because that's all I and the last 1 is a high potential report of all I'm to us is a more negative conversely means a is the redox couples if the matrix having a smaller error and show that and Europe on them them there use speech is provided if the matrix has a great attention than do on them than what the oxidized species breed this statement is generally to what each rest of the red potential of a marriage rates and called is an equally important parameter at pH 4 note that any information from the transfer reaction can be found in the the calculation of the potential on culminated loop the circulating
number of the tongue and that the emitted numbers of all reactants and products have to be taken into
in gas shows special of among mathematics through 3 phases have been called and deadliest especially then they would think you and every time conducted a solid the huge but that the grammar of including the chemistry the hydrogen that's calculated potentially announced by definition of that potential is the Europe there are 2 electrons involved enough that but to divide us from where all the growth on concentration by the hydrogen content according to the convention a combination of guests like hydrogen has is specified in the unit by and the concentration of dissolved species by proton at this that fight in moles per year a medical disease
into their just merge a metal in his solution of the night vision for a said Atle would be as follows you to extend the period if you require a lot of and the reduction of 1 of the transfer reactions YouTube and all over and with a concentration of a set of all I hand over the concentration of the as a matter of this is of they to use the unit mole fraction suspected by cover and he is pure so the mole fraction is equal to 1 so we may omit this concentration all until we have the concentration of
solid may always be omitted no that is not true for vacant-eyed reference it builds the local alright this is not a real basis the combined natural experiment on the soul of man and in July because 1 in mind and 1 equation with 2 can be expressed as follows near a point 2 2 bald follows standards but then should you know is equal equals to 1 we have to divide the
concentration of solids civil law right the model rational but concentration of a solid the ball also move action again and the concentration of chloride ions the molar concentration in moles per liter classical reference electrodes in chemistry or the standard hydrogen electrode and key with Europe on the review of your was Euro the panel and you would with your 1 2 4 1 wall and so-called saturated so the fewer comma decimal 1 7 9 4 miniaturized Filipino-Americans
may be used in macroscopic applications that measuring potentials in biological sets the potential of
single atoms to the dimension in contrast to their friends in rare earth potential of into it so many times very easily combining the troops with a couple of you who it last good right saddled the Daniel this led to the last cell We twice the 9th equation both what node and have the couple had a high potential and that thus is a positive number gain can monitor potential and in the negative tongue at conferences at times will voluntarily removed from the metal into the electoral it loses the pattern
at the intended to Exxon's were possible voluntarily interface model in light in the opposite direction and the boy to jobs the the potential
difference we can measure corresponds to the difference between carefully attention and and 1 method of
noble circuit bondage call this potential differences better be what he and I have quoted promoted people's each battery is about myself I would just about every province those exactly as thrown here and they don't have the producers of a woman to have it if we want to challenge the batteries we reverse the colander and Asia further has to be solved and the whole of Europe but channels that being will be negative the a look at the potential drop pride in open source starting out of the metals with the lowest potential serious about tension jaundicing in her passing the salt bridge you arrive at a public lecturer in a 1st approximation of
many their junction John followed by the job and potentially into the column what we can measure with a what meter is the total potential difference between name matter and column on the Net motif
also 1 comma decimal 1 was obtained but back in the potential of using a through negative view of point 7 6 and the potential of copper goes over to you want people if that is so this is oxidized and popularized oranges this reaction may be carried out in a much easier way without Evropsko of access by simple immobilizing sink into copper solid solution then the
spontaneous for a reaction at on movement is involved too but in the following micro non directional current which cannot be used for doing that can work only in the space separation of oxidation and reduction by building a of solvent to it goes it is possible to combine these might propose as asking the figure in
general a device cell be build up from any we don't performing the reduced reaction is spontaneous we're going to hold and you that age as it heats performed the same we don't process
reversible married but in England Maxell we obtain gives free energy that energy and and yet the key times t as he of
Conley yeah after the of I fell asleep to gives free energy every temperature dependence of the the the the over T to enter that can relate common and they permeable for them yourself in here now for 21 21 companies that used 1 Pondview and on a small gives it gives free energy change on variety of negative 204 cajoles animals the
package regional negative 80 microblogs because it here's another changeup negative 15 he promoted and can you really did have vision you may
also character Apple the change their age is needed 270 you have to
using electrochemical theory we may predict spontaneity of redox there does oxygen oxidizes pH set we
screwed up and we don't reaction into 2 half reactions the oxidation and reduction I don't have a corresponding potential does the
back-end important for chemical spontaneity oxygen having more positive reduction potential and it may very well from match the answer the phones the reaction may proceed the obtain useless for
this reason corrosion of paraffin period the breath of oxygen can be a problem even oxygen-free water can oxidize some metals at pH that all matter which of in the world but I and maybe effect mutual water containing oxygen has a much stronger oxidizing power it may oxidize all which Nobel son
relations facilitated by the following conditions but none of oxygen no pH high conductivity of the polite and lots of potential difference in the material with the potential
difference in material all with the piano itself for the cathode is protected from courage by using a
sacrificial metal all the
lines down waters we can make them until have and thus protected from the ocean we speak of the P. coupling protection contact
macromolecular you build of only 2 and create a potential jump at the boundary unchecking to extradite but also resulted advantage this is called a liquid junction potentials maple and separated
the debt from concentrating hydrochloric acid solutions by the poorest areas
Nobel protons and chloride and will you use from the more concentrated solution to the less concentrated too because protons
diffuse much faster than the ahead is the solution using the positively charged but junction
potentials Medicare-related carefully from Republican mobilities of from the grasp of numbers she's of cast iron and and I only in and I think and moderated the same speed but when T plus key minus equal to 0 comma decimal 5 the liquid junction but that's the way this is why I put that thing right and we should or ammonium not solutions are widely used in solitary if a seperate 2
different constant very high priority at solutions bias thing in terms of the membrane only the protons may pass the membrane we also get a better job at the phase boundary with
with bigger done what which can have related with the formula which is very similar to the junction tree the
the potential may be used for analytical purposes or the Apple and latitude or determining pH it more and have made
the membrane this equation valid for each there is no other relationship between the concentrations of the 9 which is referred to as the dominant the protocol accommodation of the eye and
the left hand side of the membrane is equal to the power of the concentrations of all the lines on the right hand side but the benches on important in by to
summarize any combination of neutron a conductor and an ionic conductor is negative know those characterized by an atom transfer reaction it included when
the holiday and on the columns of equal the rest potential of even they may have the with non equation there is a lot of
differences describes the quantity of of substance liberated ontologies on the thank you for watching by
Zelle
Physikalische Chemie
Phasengleichgewicht
Potenz <Homöopathie>
Topizität
Chemische Forschung
Ordnungszahl
Ionenbeweglichkeit
Chemische Reaktion
Eisenherstellung
Aktionspotenzial
Ionenbindung
Elektronentransfer
Physikalische Chemie
Zellmigration
Elektrolyse
Spezies <Chemie>
Katalase
Metallatom
Reduktionsmittel
Elektron <Legierung>
Reaktionsführung
Oxidschicht
Elektronentransfer
Linker
Durchfluss
Ordnungszahl
Medroxyprogesteron
Hyperpolarisierung
Kupfer
Zelle
Chlor
Wasserfall
Reduktionsmittel
Kupferchloride
Redoxsystem
Aktivität <Konzentration>
Oxidschicht
Elektronegativität
Abbruchreaktion
Umweltchemikalie
Chemischer Prozess
Zelle
Wasserfall
Primärelement
Reduktionsmittel
Elektronegativität
Abbruchreaktion
Aceton
Azokupplung
CHARGE-Assoziation
Verhungern
Reaktionsführung
Allmende
Katalysator
Brandsilber
Stoffmenge
Schussverletzung
Aktionspotenzial
Strom
Nobelium
Kluftfläche
Ionenbindung
Linker
Mähdrescher
Chemischer Prozess
Inlandeis
Aktionspotenzial
Azokupplung
Kupfer
Wasserfall
Elektron <Legierung>
Eisenherstellung
Bewegung
Desublimation
Selenite
Chemischer Prozess
Strom
Chemische Struktur
Primärelement
Metallatom
CHARGE-Assoziation
Elektron <Legierung>
Oktanzahl
Medroxyprogesteron
Lösung
Aktionspotenzial
Kupfer
Elektronentransfer
Konzentrat
Radioaktiver Stoff
Elektrochemisches Verfahren
Verhungern
Reaktionsführung
Topizität
Medroxyprogesteron
Aktionspotenzial
Spezies <Chemie>
Elektron <Legierung>
Konzentrat
Aktionspotenzial
Spezies <Chemie>
Reaktionsführung
Aktionspotenzial
Azokupplung
Spezies <Chemie>
Bezugselektrode
Reduktionsmittel
Trennverfahren
Reaktionsführung
Oxidschicht
Setzen <Verfahrenstechnik>
Membranpotenzial
Nichtmetallverbindungen
Operon
Druckausgleich
Medroxyprogesteron
Azokupplung
Reaktionsführung
Alkoholgehalt
Disposition <Medizin>
Aktionspotenzial
Reaktionsführung
Modul <Membranverfahren>
Oktanzahl
Metallmatrix-Verbundwerkstoff
Konzentrat
Explosivität
Medroxyprogesteron
Konkrement <Innere Medizin>
Aktionspotenzial
Spezies <Chemie>
Redoxsystem
Eisenherstellung
Thermoformen
Elektronentransfer
Lactitol
Chemische Forschung
Protonierung
Spezies <Chemie>
Hydrierung
Zellwachstum
Elektron <Legierung>
Phasengleichgewicht
Mähdrescher
Konzentrat
Gesundheitsstörung
Aktionspotenzial
Metallatom
Single electron transfer
Stoffmengenanteil
Reduktionsmittel
Reaktionsführung
Mannose
Elektronentransfer
Zuchtziel
Konzentrat
Periodate
Lösung
Chemische Forschung
Silberchlorid
Single electron transfer
Tiermodell
Bezugselektrode
Molvolumen
Konzentrat
Chloridion
Medroxyprogesteron
Aktionspotenzial
Azokupplung
Grenzfläche
Zelle
Tiermodell
Metallatom
Elektronegativität
Ordnungszahl
Seltenerdverbindungen
Medroxyprogesteron
Chemischer Prozess
Aktionspotenzial
Wassertropfen
Edelgas
Metallatom
Ionenkanal
Primärelement
Kochsalz
Aktionspotenzial
Kupfer
Reaktionsführung
Elektronegativität
Zellkontakt
Orangensaft
Mischkristall
Chemischer Prozess
Aktionspotenzial
Altern
Zelle
Redoxsystem
Reaktionsführung
Apothekerin
Tellerseparator
Chemischer Prozess
Körpertemperatur
Arginin
Gibbs-Energie
Rösten
Selbstentzündung
Anomalie <Medizin>
ARS-Element
Altern
Arginin
Redoxsystem
Reaktionsführung
Oxidschicht
Selbstentzündung
Aktionspotenzial
Sauerstoffverbindungen
Metallatom
Nobelium
Reaktionsführung
Zündholz
Redoxpotential
Potenz <Homöopathie>
Selbstentzündung
Wasser
Korrosionsbeständigkeit
Periodate
Sauerstoffverbindungen
Krankheit
Sauerstoffverbindungen
Aktionspotenzial
Meer
Azokupplung
Metallatom
Zellkontakt
Wasser
Aktionspotenzial
Protonierung
Chloride
Nobelium
Querprofil
Eisenchloride
Zellkontakt
Lösung
Protonierung
Phasengleichgewicht
Grauguss
Ammoniumverbindungen
Zellkontakt
Plasmamembran
Chemischer Prozess
Lösung
Aktionspotenzial
Chemische Formel
Zellkontakt
Konzentrat
Plasmamembran
Aktionspotenzial
Atom
Reaktionsführung
Potenz <Homöopathie>
Elektronentransfer
Linker
Mähdrescher
Konzentrat
Plasmamembran
Aktionspotenzial

Metadaten

Formale Metadaten

Titel Electron transfer reactions and redox potentials in GALVANIc cells - what happens to the ions at the phase boundary (NERNST, FARADAY)
Serientitel Physical Chemistry
Autor Lauth, Günter Jakob
Mitwirkende Lauth, Anika (Medientechnik)
Lizenz CC-Namensnennung - keine kommerzielle Nutzung 3.0 Deutschland:
Sie dürfen das Werk bzw. den Inhalt zu jedem legalen und nicht-kommerziellen Zweck nutzen, verändern und in unveränderter oder veränderter Form vervielfältigen, verbreiten und öffentlich zugänglich machen, sofern Sie den Namen des Autors/Rechteinhabers in der von ihm festgelegten Weise nennen.
DOI 10.5446/34660
Herausgeber Günter Jakob Lauth (SciFox)
Erscheinungsjahr 2013
Sprache Englisch

Inhaltliche Metadaten

Fachgebiet Chemie, Physik

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