Lecture 15. Hofmann Degradation, Diazotization, & Aryl Diazonium Salts. - TIB AV-Portal

Lecture 15. Hofmann Degradation, Diazotization, & Aryl Diazonium Salts.

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University of California Irvine (UCI)

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Lecture 15. Hofmann Degradation, Diazotization, & Aryl Diazonium Salts.

Title of Series

Chemistry 51C: Organic Chemistry (Spring 2012)

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15

Number of Parts

19

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CC Attribution 3.0 Unported:
You are free to use, adapt and copy, distribute and transmit the work or content in adapted or unchanged form for any legal purpose as long as the work is attributed to the author in the manner specified by the author or licensor.

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10.5446/19419 (DOI)

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University of California Irvine (UCI)

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Abstract

This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 2:13-Alkylation 10:19-Hofmann Degredation 14:56-Silver Oxide and Water 16:43-Hofmann Elimination 17:18-E2 Elimination 24:29-Conventional E2 Elimination 26:47-Elimination Example 31:29-2-bromobutane Example 36:39-Aromatic Chemistry 40:21-Diazotization Reaction 52:12-Diazonium Ion Reactivity 55:29-Dizonium Salt Reactions 1:05:05-Synthesis Examples 1:18:27-Alkyl Diazonium Salts are Unstable 1:19:53-Nitrosamines

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Hydroxybuttersäure <gamma->CigarElectronic cigaretteChemistrySystemic therapyAminationAlkylationHaloalkaneChemical compoundLeadChemical reactionMixtureAmineAmmoniaTiermodellHalidePharmacyAlkaneController (control theory)AmineBase (chemistry)MethylgruppeLecture/Conference

02:23

ArylCigarMagnetometerChemical engineeringMethyl iodideAlkylationElectrical breakdownAlkaneHalideChemical reactionBromideChemical compoundMethylchloridMethylgruppeAmineBenzylMixtureLecture/Conference

03:28

Herzog August LibraryMan pageHydroxybuttersäure <gamma->DelicatessenAnomalie <Medizin>ElfMethylgruppeSaltAmmonium iodideChemical reactionAmmoniumOrganische ChemieMethyl iodideBiosynthesisAlkylationStop codonBase (chemistry)Lecture/Conference

04:39

ProtonationMethylgruppeChemistryIodideMoleculePharmacyBase (chemistry)Potassium carbonateAmineMethyl iodideAmmonium iodideSaltGesundheitsstörungMedical historyMixtureLecture/Conference

05:51

AcylCigaretteChemical propertySurfactantQuaternary ammonium cationSolutionSetzen <Verfahrenstechnik>AmmoniumSaltDrop (liquid)MoleculeCell membraneAugentropfenWine tasting descriptorsAlkylationStickstoffatomSubstituentBiomolecular structureAminationLecture/Conference

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Man pageBattery (electricity)Schweflige SäureMethyl iodideElectronic cigaretteConjugated systemBase (chemistry)ChloridePhenolStickstoffatomAromaticitySubstitutionsreaktionBenzeneHalogenElectronAcidAluminium chlorideSetzen <Verfahrenstechnik>BiosynthesisChemical reactionKatalaseKorngrenzeChemical elementFormaldehydePolymerAngiotensin-converting enzymeAldehydeAnilineAmineAcylAluminiumProteinkinase ABenzylSchwefelblüteProtonationButylCarbokationLone pairWine tasting descriptorsLecture/Conference

10:18

Man pageTable wineHydroxybuttersäure <gamma->ChemistryConformational isomerismChemical reactionStereochemistryPharmacyLactitolSunscreenHydrogenMorphineKohlenhydratchemieCombustibilityMoleculeChemical structureReaction mechanismSpectroscopyGeochemistryLecture/Conference

11:32

Man pageSodium hydrideMethylgruppeHydroxidePotassiumAmmonium hydroxideOxideBiomolecular structureWaterAmmonium iodideSolutionEthyleneMethyl iodideOrganische ChemieIodideProtonationWalkingBoilingReaktionsgleichungChemical compoundStorage tankBase (chemistry)SilverAlkylationTrimethylaminEthylgruppeAmineIodineLecture/Conference

13:39

Ethylene-vinyl acetateBattery (electricity)TanningOxideOxideSilverWaterAldehydeHydroxideCarboxylateCarboxylierungLecture/Conference

14:56

Man pageGraukäseSodium hydrideDye penetrant inspectionMoleculeSilverOxideHydroxideSilver iodideSilver bromideSilver chlorideChemical reactionBromideHalogenChlorideIodideIodoformThermoformingEthylgruppeTrimethylaminChemistrySaltAlkylationAmmoniumMethylgruppeWaterAmmonium hydroxideBreed standardOrganische ChemieAmmonium iodideLecture/Conference

16:24

Man pageMagnetometerHistologySodium hydrideEliminierungsreaktion <beta->Organische ChemieSaltWalkingProcess (computing)SpeciesChemical reactionPrecipitation (chemistry)AmmoniumMethylgruppeHydroxideProtonationFunctional groupIonenbindungFermentation starterElectronWaterTrimethylaminEthylgruppeEthyleneCarbon (fiber)IodideLone pairBase (chemistry)ExplosionAmmonium iodideElectronic cigaretteLecture/Conference

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Man pageMethylmalonyl-CoA mutaseHistologyArginineAdder stoneMashingMagnetometerPropionaldehydMethyl iodideOxymercurierungEliminierungsreaktion <beta->StuffingCocaineHydroborierungController (control theory)KaliumhydroxidOxideEthylgruppeChemistryGlättung <Oberflächenbehandlung>DoppelbindungBiomolecular structureIonenbindungHydrogenSodium hydroxidePotassium carbonateChemical reactionFunctional groupWaterGesundheitsstörungHydroxideHybridisierung <Chemie>MolecularityPeriodateButyraldehydeWaterfallReducing agentGeochemistrySystemic therapyGemstoneAreaLecture/Conference

21:54

Mur, SwitzerlandRiver mouthChemistryEliminierungsreaktion <beta->SilverFood additiveMoleculeKaliumhydroxidWaterOxideHexaneMethylgruppeActivity (UML)Biomolecular structurePotassium carbonateLeadAmmoniumMethyl iodideÜbergangszustandIodideAlkeneStereoselectivityCyclohexanFunctional groupPotassiumLecture/Conference

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Man pageVolumetric flow ratePharmacyOperonBiosynthesisController (control theory)OxideBiomolecular structureHybridisierung <Chemie>Chemical elementHydroborierungMan pageSetzen <Verfahrenstechnik>ChemistryEliminierungsreaktion <beta->StereochemistryAlkeneLecture/Conference

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Man pageHydroxybuttersäure <gamma->MagmaKalisalzeAlgal bloomMethylgruppeKaliumhydroxidAmmonium iodideAmmoniumHydroxideEliminierungsreaktion <beta->DoppelbindungHydrogenLone pairIodideCyclohexanTrimethylaminLecture/Conference

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Hydroxybuttersäure <gamma->MagnetometerChemical structureHexaneMethylgruppeFunctional groupArzneimitteldosisCycloalkaneAmmoniumHydrogenOctane ratingEliminierungsreaktion <beta->MoleculeTrimethylaminCyclohexanConformational isomerismLecture/Conference

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Man pageHydroxybuttersäure <gamma->HydrogenTrimethylaminPeriodateAmmoniumMethylgruppeHydroxideEliminierungsreaktion <beta->Lecture/Conference

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Electronic health recordEliminierungsreaktion <beta->ChemistryDeterrence (legal)StuffingAlkeneHydrogenSodiumMetalSodium oxideButadienEthanolBase (chemistry)AlkaneHalideLecture/Conference

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Man pageMethylmalonyl-CoA mutaseMagnetometerMashingEliminierungsreaktion <beta->BiosynthesisHalideBase (chemistry)EtherMixtureChemical reactionAlkeneCarcinoma in situElectrical breakdownSubstitutionsreaktionÜbergangszustandButyraldehydeLecture/Conference

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ButyraldehydeMethyl iodideRiver deltaSilverWaterAlkenePotassium carbonateSetzen <Verfahrenstechnik>OxideGesundheitsstörungChemistryReducing agentHydro TasmaniaController (control theory)OxideOxymercurierungHydroborierungLecture/Conference

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Sodium hydrideMan pageIsomerMixtureCarcinoma in situCell (biology)MalerfarbeChemistryEliminierungsreaktion <beta->SubstitutionsreaktionElectronOrganische ChemieAromaticityBottling lineEnantiomereAtomic orbitalLactitolAminationLecture/Conference

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Man pageMethylmalonyl-CoA mutaseTolueneBenzeneSubstitutionsreaktionMolekulardynamikPetroleumXyleneRiver sourceNaphthalinIronChemistryReducing agentSalpetersäureToluidineStickstoffatomChemische IndustrieChemical compoundPalladiumHydrogenCarbon (fiber)Tin canSchweflige SäureHydrierungNitrierungHydrogen chlorideAminationAmineAcidNitroverbindungenStockfishLecture/Conference

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Man pageSodium hydrideTrivialnameTolueneAnilineToluidinePhenolSynthetic oilWalkingDreifachbindungMolecularityStickstoffatomChemistryNitrateSaltSodium nitriteSetzen <Verfahrenstechnik>Functional groupNucleophilic substitutionAcidCarbokationDiazonium compoundSodiumLecture/Conference

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Man pageMagnetometerSodium hydrideChemistryDiazonium compoundChemical reactionSodiumNitriteSaltAcidWaterIronAssetChemical structureSalpetrige SäureHydrogen chlorideProtonationLecture/Conference

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Man pageBis (band)Schweflige SäureSubstitutionsreaktionAcidReaction mechanismStickstoffatomMoleculeSalpetersäureProtonationHydroxylSodiumHeck-ReaktionElectronSpeciesWaterLactitolCobaltoxideResonance (chemistry)Lone pairInorganic chemistryChemical structureOrganische ChemieAgeingAtom probeLecture/Conference

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ThermoformingSpeciesIonenbindungChemical compoundOrganische ChemieCobaltoxideElectronWaterGeneric drugStickstoffatomWursthülleBenzeneAmineChemical reactionSodiumLone pairArylAromaticityFunctional groupHome remedyLecture/Conference

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Herzog August LibraryProtonationElectronAssetLone pairAcidChlorideBase (chemistry)Functional groupChemical compoundGesundheitsstörungHydrogenElectronic cigaretteStickstoffatomWaterAmineAmineNitrosamineCarcinogenLecture/Conference

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Man pageHydrogenAlpha particleNitrosamineAcidChemical compoundHydrocarboxylierungKetoneNitrosoverbindungenOcean currentProtonationStickstoffatomMoleculeReaktionsgleichungReaction mechanismElectronLone pairAmmoniumAgeingWaterWalkingActive siteBiomolecular structureVolumetric flow rateCobaltoxideChemistryResonance (chemistry)SpeciesDreifachbindungBase (chemistry)Diazonium compoundTautomerLecture/Conference

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MixtureFunctional groupCobaltoxideChemistryReaction mechanismDiazonium compoundRecreational drug useHydrocarboxylierungStickstoffatomHeteroatomProtonationAmmoniumDeformityWursthülleSpeciesValenzelektronLone pairSodium nitriteNitroverbindungenHydrogenSodiumCarbon (fiber)BenzeneIonenbindungBottling lineReaktionsgleichungChemical plantCarbokationGeneric drugArylLecture/Conference

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Table wineZeitverschiebungReaktionsgleichungAtomic orbitalISO-Komplex-HeilweiseChemistryElectronWursthülleRepeated sequence (DNA)CopperAtomic orbitalChemical reactionSchweflige SäureWaterSodium nitriteStickstoffatomGesundheitsstörungAcidIceHydrochloric acidLeakHuman body temperatureLecture/Conference

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Chemical reactionWaterAgeingHuman body temperatureEthanolAageBenzeneChemical compoundProtonationHydroxylChemistryReducing agentAromaticityDiazoPhenolsLecture/Conference

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Nitrogen fixationReaction mechanismMetallorganische ChemieChlorineChloridePolymorphism (biology)LambicChemistryHydrogen chlorideHydrochloric acidChemical reactionOrganische ChemieSodium nitriteCopper(II) chlorideSeparator (milk)SodiumCopperFiningsIonenbindungCyanidionAcylAcidAlkylationStickstoffatomBromideAnimal trappingSchweflige SäurePhenolMixtureSodium nitrateIslandCyanideCopper(I) cyanideAageChemical reactorRiver sourceFunctional groupGesundheitsstörungOctane ratingOrganic semiconductorMixing (process engineering)CooperativityLecture/Conference

01:00:51

Killer-cell immunoglobulin-like receptorMan pageChemical reactionAlkaneChemistryAzo couplingLaundryAtomBenzeneAdamantaneFluorineSodiumPhosphinsäureFluorideMoleculeRecreational drug useCarbokationSodium nitriteChemical propertyFiningsHydrogenAcidRiver sourceHydrideTolueneHydrogen chlorideEPDM rubberBorsäureChlorineNaphthalinLecture/Conference

01:03:52

Man pageChemical reactionCobaltoxideElectronHydrideRiver sourceAdamantanePhosphorusPhosphorous acidAtomHydrogenChemistryNitroverbindungenExciter (effect)AromaticityRedoxLecture/Conference

01:05:08

SyrupPhenolBenzeneAromaticityMoleculeSubstitutionsreaktionTolueneChain (unit)Setzen <Verfahrenstechnik>BiosynthesisFirePetroleumLecture/Conference

01:06:51

Man pageSecondary ion mass spectrometryCarbokationSubstitutionsreaktionResonance (chemistry)Food additiveCobaltoxideAgeingChlorinePhenolAromaticityChlorideIronOperonLecture/Conference

01:08:42

Man pageLavaChemical compoundOperonController (control theory)Block (periodic table)Potenz <Homöopathie>Recreational drug usePharmacyChlorinePhenolChlorphenoleMoleculeAgeingActivity (UML)Lecture/Conference

01:10:34

Table wineRiver sourceNitroverbindungenFunctional groupNitrobenzolController (control theory)HolzfaserwerkstoffChemical reactionChlorideChemistryStickstoffatomLecture/Conference

01:11:37

Man pageSodium hydrideFatty acid synthaseValineAreaPalladiumCarbon (fiber)AnilineChemical reactionSaltAcidWaterRiver deltaSchweflige SäurePhosphorusPhosphorous acidPhosphinsäureDiazonium compoundLecture/Conference

01:12:48

Man pageVancomycinMedroxyprogesteronePhenolChlorineStuffingLecture/Conference

01:14:00

BromineBromobenzeneProtein domainBenzeneActivity (UML)Flash evaporationAmineLecture/Conference

01:15:18

ChlorineBromineFlash evaporationEliminierungsreaktion <beta->AnilineController (control theory)Chemical reactionWursthülleIronDünnschichtchromatographieEisenbromideLecture/Conference

01:16:25

MagmaFunctional groupAmineIronBromideBrominePhosphorous acidController (control theory)PhosphorusWine tasting descriptorsBenzeneAcidStickstoffatomAgateSodium nitriteSchweflige SäureChemistryElectronAromaticityChemical compoundAssetLone pairAgeingLeadAlcoholKatalaseSeleniteFormaldehydeGesundheitsstörungAreaDiet foodThermoformingHydrogen chlorideAminationDiazonium compoundAmineSodiumCarbokationIceAlkylationSaltLecture/Conference

01:19:49

Man pageChemistryTautomerReaction mechanismChemical compoundHydrogen chlorideResonance (chemistry)StickstoffatomGesundheitsstörungDimethylaminNitrosamineSodium nitriteNitrosoverbindungenAmineLecture/Conference

01:20:53

MeatDNS-SyntheseNitriteCarcinogenSubstitutionsreaktionNitrosamineChemistryDiazonium compoundDyeCancerLecture/Conference

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