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Lecture 10. Enols and Enolates.

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Logo of University of California Irvine (UCI)University of California Irvine (UCI)
 Nowick, James

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Lecture 10. Enols and Enolates.
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10
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19
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CC Attribution 3.0 Unported:
You are free to use, adapt and copy, distribute and transmit the work or content in adapted or unchanged form for any legal purpose as long as the work is attributed to the author in the manner specified by the author or licensor.
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Abstract
This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 1:16-Reactivity of Ketones 3:02-Enols 6:36-Enolate Anion 9:47-Enolates and Electrophiles 16:49-Equilibrium Between Tautomers 23:07-Acid-Catalyzed Enol Formation 29:18-Energy Diagram 37:51-Multiple Additions 46:41-pKa of Alpha Protons 53:05-Base-Catalyzed Enol Formation 58:56-Stereochemistry 1:03:42-LDA 1:11:28-Kinetic Product vs Thermodynamic Product 1:17:56-LDA and Stereochemistry