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Lecture 23: Lindemann-Hinshelwood Part I

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Logo of University of California Irvine (UCI)University of California Irvine (UCI)
 Penner, Reginald

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Lecture 23: Lindemann-Hinshelwood Part I
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23
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27
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UCI Chem 131C Thermodynamics and Chemical Dynamics (Spring 2012) Lec 23. Thermodynamics and Chemical Dynamics -- Lindemann-Hinshelwood Part I -- Instructor: Reginald Penner, Ph.D. Description: In Chemistry 131C, students will study how to calculate macroscopic chemical properties of systems. This course will build on the microscopic understanding (Chemical Physics) to reinforce and expand your understanding of the basic thermo-chemistry concepts from General Chemistry (Physical Chemistry.) We then go on to study how chemical reaction rates are measured and calculated from molecular properties. Topics covered include: Energy, entropy, and the thermodynamic potentials; Chemical equilibrium; and Chemical kinetics. Index of Topics: 0:00:06 Lindermann-Hinshelwood 0:03:46 The Steady-State Approximation 0:21:26 Two Limiting Experimentally Observed Rate Laws 0:24:40 Elementary Reactions 0:31:10 The Strong Collision Assumption 0:38:04 The Kinetics of Pressure-Dependent Reactions 0:45:44 Reactions Where a Pre-Equilibrium is Established