We're sorry but this page doesn't work properly without JavaScript enabled. Please enable it to continue.
Feedback

Visible light mediated deoxygenations

Formal Metadata

Title
Visible light mediated deoxygenations
Title of Series
Number of Parts
163
Author
License
CC Attribution - NoDerivatives 4.0 International:
You are free to use, copy, distribute and transmit the work or content in unchanged form for any legal purpose as long as the work is attributed to the author in the manner specified by the author or licensor.
Identifiers
Publisher
Release Date
Language

Content Metadata

Subject Area
Genre
Abstract
We introduce here a protocol for deoxygenation of alcohols by photoredoxcatalysis with visible light, which allows the recycling of the activating agent under redoxneutral conditions. About 60 % of all biomass on earth are carbohydrates, i.e. polyhydroxylated compounds. Removing these hydroxyl groups would be desirable to arrive at compounds that might be used as biofuels or that might be further functionalized by chemistry that has been established in the last century based on fossil starting materials (oil and gas). Chemical deoxygenations however are difficult due to the high stability of the carbon-oxygen bond, which requires activation that in turn produce waste in (over)stoichiometric amounts that cannot be easily recycled. We introduce here a protocol for deoxygenation of alcohols by photoredoxcatalysis with visible light, which allows the recycling of the activating agent under redoxneutral conditions. Moreover, in situ activation and deoxygenation is possible in a flow setup, being attractive for large-scale applications.
Keywords