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Alternatives to Direct Alkylation of Enolate Ions

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Logo of University of California Irvine (UCI)University of California Irvine (UCI)
 King, Susan

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Alternatives to Direct Alkylation of Enolate Ions
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15
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27
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CC Attribution - ShareAlike 3.0 USA:
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Abstract
This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:21 - Base Promoted Halogenation of Aldehydes and Ketones 11:46 - Alpha Halogenated Carbonyl Compounds in Synthesis 17:55 - Direct Alkylation of Enolate Ions 27:44 - Kinetic vs Thermodynamic Enolate 43:45 - Alkylation and Acylation of the Alpha Carbon via an Enamine Intermediate