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Surface rippling induced by periodic instabilities on a polymer surface

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Titel
Surface rippling induced by periodic instabilities on a polymer surface
Serientitel
Anzahl der Teile
62
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Lizenz
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Identifikatoren
Herausgeber
Erscheinungsjahr2015
SpracheEnglisch

Inhaltliche Metadaten

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Genre
Abstract
When the shear stress on a compliant surface exceeds the yield strength of the material, a periodic wrinkle pattern is often observed. This phenomenon has been also recognized at the nanometer scale on polymers, metals, ionic crystals and semiconductors. In those cases, the mechanical stress can be efficiently provided by a sharp indenter elastically driven at constant velocity along the surface. Here we suggest that the formation of such surface ripples can be explained by the competition between the driving spring force and the plastic response of the substrate. In particular, we show how the ripples are expected to disappear when the indentation rate is below a critical value or, alternatively, when the sliding velocity or the lateral stiffness of the contact are too high. The model results are compared to atomic force microscopy experiments on a solvent-enriched polystyrene surface, where the rippling formation is enhanced at room temperature, compared to bulk melts. A similar approach could be employed to describe rippling phenomena on larger scales.