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Lecture 20. Radicals

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Lecture 20. Radicals
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20
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26
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Abstract
This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken. Index of Topics: 00:17- Pycnogenol 00:42- What is Pycnogenol? 01:11- Molecular Structure of Pycnogenol 03:22- 14.8: Splitting by More than One Type of Proton 07:55- 14.9: Time Dependence of H NMR Spectroscopy-Bond Rotation 09:42- 14.9: Time Dependence of H NMR Spectroscopy CHAPTER 15- Radicals 15:37- 15.1: Radicals-Reactivity and Stability 21:04- 15.1, 15.2: Reactions of Radicals-a specialized arrow symbol 24:55- 15.3, 15.6, 15.7: Selective conversion of tertiary R-H to tertiary R-Br 29:35- 15.4: Mechanism for Radical Bromination 36:26- 15.8: Carbon radicals react on either end of the p orbital 42:15- 15.10: Allylic Bromination 48:06- 15.13: Anti-Markovinkov of HBr to H2C=CHR 50:39- Chapter 15-Radical Summary