Show filters Hide filters

Refine your search

Publication Year
Person found in the video
1-36 out of 52 results
Change view
  • Sort by:
49:12 University of California Irvine (UCI) English 2015

Wittig Reaction

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:23 - Summary of Addition Reactions of Aldehydes & Ketones 03:39 - Addition of a Phosphonium Ylide (Wittig Reaction) 18:14 - Retrosynthetic Analysis 25:13 - Addition of Weak Nucleophiles 35:00 - Synthesis Example 39:53 - Structure and Physical Properties of Carboxylic Acid Derivatives 47:47 - Some Famous Type 2 Carbonyl Compounds
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:20 University of California Irvine (UCI) English 2015

Addition of Water, Alcohol & Cyanide

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:25 - Addition of Alcohols 04:35 - Important Points about Acetal and Hemiacetal Formation 17:26 - Cyclic Acetals are formed more readily than Acyclic Acetals 21:30 - Addition of HCN 27:10 - Addition of Primary Amines (R-NH2) to give Imines 45:17 - Addition of Secondary Amines (R2NH) to give Enamines
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:25 University of California Irvine (UCI) English 2015

Aldehydes & Ketones: Nucleophilic Substitution

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 01:51 - Designing Syntheses 10:17 - Some Famous Type 1 Carbonyl Compounds 12:23 - Physical Properties of Aldehydes & Ketones 15:24 - Reversible Addition Reactions of Aldehydes & Ketones 16:05 - Addition of Water (Hydration) 37:24 - Base Catalyzed Addition of Alcohols 41:11 - Acid Catalyzed Addition of Alcohols 43:54 - Step 1: Hemiacetal Formation 46:30 - Step 2: Acetal Formation
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:41 University of California Irvine (UCI) English 2015

The Claisen Condensation

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:36 - Synthesis with the Aldol Condensation 21:16 - The Claisen Condensation 32:32 - Crossed Claisen Condensation
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
48:50 University of California Irvine (UCI) English 2015

Lecture 7: Conversion of Alcohols to Alkyl Halides

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:11 - Elimination Reactions of Alcohols: Dehydration 08:02 - Carbocation Rearrangement 24:12 - Conversion of Alcohols to Alkyl Halides with H-X
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:00 University of California Irvine (UCI) English 2015

Alternatives to Direct Alkylation of Enolate Ions

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:21 - Base Promoted Halogenation of Aldehydes and Ketones 11:46 - Alpha Halogenated Carbonyl Compounds in Synthesis 17:55 - Direct Alkylation of Enolate Ions 27:44 - Kinetic vs Thermodynamic Enolate 43:45 - Alkylation and Acylation of the Alpha Carbon via an Enamine Intermediate
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:30 University of California Irvine (UCI) English 2015

Electrophilic Addition Reactions of Type 2 Carbonyl Compounds

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:22 - Electrophilic Addition Reactions of Type 2 Carbonyl Compounds: Acyl Substitution 03:53 - Mechanism and Reactivity in Acyl Substitution Reactions 06:34 - The Stability of the Carboxylic Acid Derivative 08:15 - The Leaving Group Ability 10:30 - The Rate of Reaction 27:03 - Reactions of Acyl Halides 41:44 - Reactions of Anhydrides 49:33 - Reactions of Esters
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
47:56 University of California Irvine (UCI) English 2015

Substitution Reactions of Carbonyl Compounds at the α-Carbon

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:21 - Irreversible Addition Reactions of Type 2 Carbonyl Compounds 17:31 - Acidity of Alpha Hydrogens 19:50 - Why is the Alpha Hydrogen of a Carbonyl Acidic? 34:02 - Enolization of Carbonyl Compounds 40:33 - What Determines the Percentage of Enol at Equilibrium?
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
46:12 University of California Irvine (UCI) English 2015

Reaction of Esters

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:22 - Reactions of Esters 01:22 - Reaction of Esters with Water: Hydrolysis of Esters 01:56 - Acid Catalyzed Hydrolysis of Esters 09:22 - Base Promoted Hydrolysis of Esters 32:43 - Application: Lipid Hydrolysis 37:20 - Percent Fatty Acid in Triacylglycerides 37:56 - Reaction of Esters with Alcohols: Transesterification
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:45 University of California Irvine (UCI) English 2015

Reactions of Carboxylic Acids

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:20 - Reaction of Esters with Alcohols: Transesterification 02:03 - Reaction of Esters with Amines: Aminolysis 02:37 - Reactions of Carboxylic Acids 07:09 - Acid Catalyzed Esterification (Fisher Esterification) 14:30 - Conversion of Carboxylic Acids into Acid Chlorides 21:51 - Reactions of Amides 22:44 - Acid Catalyzed Hydrolysis of Amides 31:32 - Acid Catalyzed Esterification 32:14 - Reactions of Nitriles 45:12 - Irreverisble Addition Reactions of Type 2 Carbonyl Compounds
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
45:16 University of California Irvine (UCI) English 2015

Lecture 8: Methods for Converting Alcohols to Alkyl Halides

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:49 - Secondary and Tertiary Alkyl Halides 03:33 - Other Methods for Converting Alcohols into Alkyl Halides 31:28 - Converting Alcohols into Sulfonate Esters
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:43 University of California Irvine (UCI) English 2015

Reactions at the Alpha-Carbon

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:21 - What Determines the Percentage of Enol at Equilibrium? 05:30 - How would you completely deprotonate acetone? 10:27 - Mechanism of Keto-Enol Tautomerization: Base Catalyzed 15:55 - Mechanism of Keto-Enol Tautomerization: Acid Catalyzed 24:07 - Reactions at the Alpha-Carbon 26:39 - Racemization 31:38 - Deuterium Exchange 36:54 - Acid Catalyzed Halogenation of Aldehydes and Ketones 41:07 - Base Promoted Halogenation of Aldehydes and Ketones
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
38:25 University of California Irvine (UCI) English 2015

Carboxylic Acids

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:08 - Structure and Physical Properties of Carboxylic Acids 09:33 - Acidity of Carboxylic Acids 32:37 - Common Bases to Deprotonate Carboxylic Acids 36:48 - Oxidation of Aldehydes and 1° Alcohols 37:48 - Oxidative Cleavage of Alkenes & Alkynes: Ozonolysis
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:18 University of California Irvine (UCI) English 2015

Preparation of Carboxylic Acids

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:43 - Oxidation of Alkyl Groups Bonded to Aromatic Rings 03:31 - Sulfonic Acids 09:33 - Reactivity of Carbonyl Compounds 11:57 - Type 1 of Carbonyl Compounds 15:01 - Type 2 of Carbonyl Compounds 16:14 - Both Type 1 and Type 2 Carbonyl Compounds are Electrophilic 32:46 - Both Type 1 and Type 2 Carbonyl compounds are weakly basic at the carbonyl oxygen and protonated by strong acids 41:07 - Both Type 1 and Type 2 carbonyl compounds are acidic 44:24 - Reactivity of the various Type 1 and Type 2 Carbonyl Compounds
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:16 University of California Irvine (UCI) English 2015

Lecture 9: Reactions of Epoxides

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:50 - Converting Alcohols into Sulfonate Esters 07:27 - Substitution Reactions of Ethers 19:07 - Reactions of Epoxides: Acid-Catalyzed Ring Opening 47:58 - Nucleophilic Ring Opening
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:30 University of California Irvine (UCI) English 2015

Lecture 16: Oxidation Reactions

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:08 - Addition of Hydrogen to Alkenes 09:17 - Hydrogenation of Other Double Bonds 12:29 - Reduction of Alkynes 17:44 - Linlar's Catalyst 20:10 - The Reduction of Polar C-X sigma bonds 29:24 - Oxidation Reactions: Oxidizing Agents 31:44 - Epoxidation 39:49 - Sharpless Asymmetric Epoxidation 43:50 - Dihydroxylation
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
46:53 University of California Irvine (UCI) English 2015

Lecture 6: Alcohols, Ethers, and Epoxides

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:47 - Introduction 04:15 - Nomenclature of Alcohols 10:47 - Nomenclature of Ethers 14:59 - Preparation of Alcohols, Ethers, Epoxides 34:06 - Elimination Reactions of Alcohols: Dehydration
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
47:57 University of California Irvine (UCI) English 2015

Oxidation Reactions of Sugars

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:50 - Ether Formation 04:09 - Esterification 06:02 - Biosynthesis of Glucose 6 Phosphate 06:46 Reducing vs Non-reducing Sugars 11:48 - Oxidizing Agent: Tollen's Reagent 15:11 - Oxidizing Agent: Bromine/H2O 21:57 - Oxidizing Agent: Nitric Acid 24:13 - The Killiani Fisher Synthesis 30:52 - The Ruff Degradation 39:30 - Reduction Reactions of Sugars 41:22 - Disaccharides
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
48:42 University of California Irvine (UCI) English 2015

Preparation of Amines

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:20 - Acidity & Basicity of Aromatic Heterocycles 01:27 - Alkylation of Amines 09:20 - Reduction of Azides - Another Route to Primary Amines 16:10 - Hydrolysis of an Imide: The Gabriel Synthesis 19:39 - Reduction of Amides & Nitriles 24:03 - Reductive Amination - Reduction of Imines and Iminium Ions 30:57 - Reduction of Nitro Compounds 41:44 - Amines are Good Nucleophiles 43:02 - Reaction of Primary Amines with Nitrous Acid
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:28 University of California Irvine (UCI) English 2015

Acidity & Basicity of Amines

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 01:04 - Famous Amines 03:13 - Reaction of an Amine as a Base 05:29 - Reaction of an Amine as an Acid 06:37 - Substituent Effects on Amine Acidity and Basicity 32:44 - Acidity & Basicity of Aromatic Heterocycles
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:13 University of California Irvine (UCI) English 2015

Fischer Projections

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:41 - Monosaccharides 01:08 - Fischer Projection 12:16 - Disaccharide 13:04 - Oligosaccharide 13:35 - Polysaccharide 14:01 - Monosaccharide can be Classified by Three Criteria 15:33 - The D Family of Sugars 17:39 - The L Family of Sugars 23:09 - Epimers 25:01 - Cyclic Structures of Monosaccharides 44:08 - Haworth Projection 45:15 - Chair Conformation
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
44:20 University of California Irvine (UCI) English 2015

The Robinson Annulation & Amines

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:45 - The Robinson Annulation: Michael Reaction Followed by Aldol 04:57 - The Robinson Annulation: Retrosynthetic Analysis 17:19 - More Organic Synthesis: Looking for Disguised Key Structural Units 37:01 - Famous Amines
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
33:29 University of California Irvine (UCI) English 2015

Polysaccharides

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 27-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor Susan King. Index of Topics: 00:20 - Reduction Reactions of Sugars 02:55 - Disaccharides 10:03 - Cellulose 12:14 - Starches 16:25 - Sweeteners, Fats, and Drugs Derived from Sugars 29:46 - Amino Sugars 30:36 - N Glycosides
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:51 University of California Irvine (UCI) English 2015

Hydride Reagents and Addition to Carbonyls

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 01:59 - Reactivity of Various Type 1 and Type 2 Carbonyl Compounds 03:09 - Order of Resonance Stabilization 16:13 - Irreversible Addition Reactions of Type 1 and Type 2 Carbonyls 24:50 - Addition of Hydride Reagents
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:23 University of California Irvine (UCI) English 2015

Alpha-Beta Unsaturated Carbonyl Compounds

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:34 - Typical Reaction with Type 2 Carbonyl 05:17 - Grignard Reagents to Synthesize Carboxylic Acids 10:49 - Summarizing Grignard Reagents, Organolithium Reagents & Cuprates 14:29 - Grignards & Organolithium Reagents do not react with Alkyl Halides 15:54 - Cuprates have their own unusual chemistry 19:12 - Alpha, Beta Unsaturated Carbonyl Compounds 24:53 - Conjugate Addition competes with Addition to the Carbonyl 33:36 - Protecting Groups in Synthesis 41:24 - Designing Synthesis
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
43:08 University of California Irvine (UCI) English 2015

Lecture 1: Introduction

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 03:27 - Course Info 14:34 - Alkyl Halides and Elimination Reactions 15:40 - Nucleophilic Substitution: Review 30:59 - Elimination Reaction 34:54 - Alkenes: Structure and Stability
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:09 University of California Irvine (UCI) English 2015

Lecture 17: Green Chemistry

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:45 - Asymmetric Epoxidation 02:11 - Oxidative Cleavage of Alkenes: Ozonolysis 09:13 - Oxidation of Alcohols: Oxidation with Chromic Acid 20:10 - Oxidation with Pyridinium Chlorochromate 24:49 - Green Chemistry 29:08 - Designing Syntheses: Part 2 40:04 - Radical Reactions: Introduction
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
51:11 University of California Irvine (UCI) English 2015

Lecture 19: Stereochemistry of Radical Reactions & Free Radical Oxidation

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:57 - Radical Substitution of Benzylic and Allylic Hydrogens 05:05 - Stereochemistry of Radical Reactions 13:10 - Radical Addition of HBr to an Alkene 24:57 - Radical Initiators 26:12 - The Peroxide Effect 30:06 - Autooxidation 37:46 - Preventing Autooxidation: Addition of Antioxidants (Free-Radical Scavengers) 39:20 - Conjugation
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
48:34 University of California Irvine (UCI) English 2015

Lecture 10: Electrophilic Addition Reaction

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:17 - Nucleophilic Ring Opening 14:32 - Alternative to Dehydration of Primary Alcohols 17:20 - Alkenes: Introduction 20:59 - Molecular Formula and Degree of Unsaturation 21:32 - Nomenclature of Alkenes 22:39 - Reactions of Alkenes: Electrophilic Addition 26:08 - Addition of Hydrogen Halides to Alkenes 40:27 - Transition State
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
47:16 University of California Irvine (UCI) English 2015

Lecture 2: Alkenes Structure and Stability

UCI Chem 51B: Organic Chemistry (Winter 2015) Instructor: Susan King, Ph.D. This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:47 - Relative Stabilities of Alkenes 11:07 - The Mechanisms of Elimination 20:10 - The Effect of the Base 21:02 - Solvent Effects 24:24 - Leaving Group Effects 25:19 - Structure of the Substrate 33:35 - Regioselectivity of the E2 Reaction: The Zaitsev Rule
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:14 University of California Irvine (UCI) English 2015

Lecture 21: Diels-Alder Reaction

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:49 - The Diels-Alder Reactions 01:32 - Characteristics of the Diels-Alder Reaction: Mechanism 02:10 - Substituent Effects 09:37 - Stereochemistry 18:41 - The Diels-Alder Reaction is Stereospecific 24:22 - The Endo Rule
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
50:15 University of California Irvine (UCI) English 2015

Lecture 14: Electrophilic Addition Reactions of Alkynes

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 01:15 - Sample Flashcards 05:33 - Acidity and s Character 14:59 - Relative Acidities 16:32 - Some Reactions after Deprotonation 21:50 - Preparation of Alkynes 30:54 - Addition of Hydrogen Halides to Alkynes 41:59 - Addition of Water to Alkynes: Hydration
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
47:59 University of California Irvine (UCI) English 2015

Lecture 12: Addition of Borane

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:09 - Addition of Bromine and Chlorine to Alkenes 07:43 - How is the enantiomer formed? 13:11 - Important points about halogen reaction 22:52 - Regiochemistry in this addition 29:14 - Addition of Borane: Hydroboration/Oxidation
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
48:54 University of California Irvine (UCI) English 2015

Lecture 18: Radical Reactions

This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 01:30 - General Features of Radical Reactions 01:54 - Reaction of a Radical X with a C-H Bond 03:47 - Reaction of a Radical X with a C=C Bond 04:58 - Radical Mechanisms 06:40 - Halogenation of Alkanes 09:16 - Mechanism 1 27:05 - Mechanism 2 31:24 - Selectivity and Stability 43:52 - Radical Substitution of Benzylic and Allylic Hydrogens
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:57 University of California Irvine (UCI) English 2015

Hydride Reagents and Addition to Carbonyls Part 2

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:24 - Alkoxide Leaving Group 01:39 - Points about Hydride Additions to Carbonyls 06:38 - LiAlH4 adds twice to Acid Chlorides 14:32 - Exactly Reducing Acid Chlorides to Aldehydes 17:59 - LiAlH4 Reduces Carboxylic Acids to Alcohols 26:43 - Converting a Carboxylic Acid to an Aldehyde 28:18 - Reducing Amides to Amines 38:33 - Stereochemistry of Carbonyl Reduction 40:21 - Chiral Reducing Agents 45:18 - Addition of Carbon Nucleophiles: Organometallic Reagents
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
49:30 University of California Irvine (UCI) English 2015

Addition of Organometallic Reagents to Carbonyls

This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Index of Topics: 00:26 - Addition of Carbon Nucleophiles 04:54 - Preparation of Organometallic Reagents 11:09 - Organometallic reagents are powerful bases 14:34 - Acidic groups that interfere with Grignard Formation 19:46 - Organometallic Reagents are Powerful Nucleophiles 24:57 - Typical Reaction with Type 1 Carbonyl 31:38 - Typical Reaction with Type 2 Carbonyl
  • Published: 2015
  • Publisher: University of California Irvine (UCI)
  • Language: English
out of 2 pages
Loading...
Feedback

Timings

  173 ms - page object
  132 ms - search
    5 ms - highlighting
    1 ms - highlighting/21632
    1 ms - highlighting/21643
    3 ms - highlighting/21606
    3 ms - highlighting/21603
    1 ms - highlighting/21650
    2 ms - highlighting/21653
    2 ms - highlighting/21633
    2 ms - highlighting/21614
    2 ms - highlighting/21651
    1 ms - highlighting/21644
    2 ms - highlighting/21627
    2 ms - highlighting/21656
    4 ms - highlighting/21604
    1 ms - highlighting/21630
    2 ms - highlighting/21610
    2 ms - highlighting/21635
    2 ms - highlighting/21613
    2 ms - highlighting/21649
    2 ms - highlighting/21616
    2 ms - highlighting/21628
    0 ms - highlighting/21655
    1 ms - highlighting/21625
    1 ms - highlighting/21626
    1 ms - highlighting/21611
    1 ms - highlighting/21641
    2 ms - highlighting/21608
    2 ms - highlighting/21631
    1 ms - highlighting/19403
    0 ms - highlighting/21642
    1 ms - highlighting/21634
    2 ms - highlighting/19404
    2 ms - highlighting/19405
    1 ms - highlighting/21647
    2 ms - highlighting/21639
    2 ms - highlighting/21640
    2 ms - highlighting/21612

Version

AV-Portal 3.8.0 (dec2fe8b0ce2e718d55d6f23ab68f0b2424a1f3f)