Understanding how colour is used by the human vision system is a widely studied research field. The field, though quite advanced, still faces important unanswered questions. One of them is the explanation of the unique hues and the assignment of color names. This problem addresses the fact of different perceptual status for different colors. Recently, Philipona and O’Regan have proposed a biological model that allows to extract the reflection properties of any surface independently of the lighting conditions. These invariant properties are the basis to compute a singularity index that predicts the asymmetries presented in unique hues and basic color categories psychophysical data, therefore is giving a further step in their explanation. In this paper we build on their formulation and propose a new singularity index. This new formulation equally accounts for the location of the 4 peaks of the World colour survey and has two main advantages. First, it is a simple elegant numerical measure (the Philipona measurement is a rather cumbersome formula). Second, we develop a colour-based explanation for the measure.